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Extra info for Adsorption from Solution
1975). Bull. Soc , Japan, _48, 324. , (1972). Soc, Faraday II, 68, 1439. E. Lane Department of Physical Chemistry University of Melbourne ParkviVie* Victoria* Australia* 3052. 1. INTRODUCTION Everett and his co-workers have made a number of important contributions to the study of surface activity coefficients. They have concentrated on relating surface activity coefficients with adsorption at the solid/solution interface. It is the intent of this contribution to consolidate these achievements, and to complement them with an examination of the relationship between the surface activity coefficients and the surface tension.
44. E. D. Thesis, Bristol. 45. V. E. (1975). Faraday Disc. Soc, 59_, 97. 46. D. W. (1981). , 7_9, 518. 47. G. (1970). H. (1971). , 35, 249; (1972). S. Faraday I, 68, 1799; (1973). 69, 1069. 48. Groszek, A. (1970). Soc, A314, 473. 49. , unpublished. 50. , unpublished. 51. Maher, P. (1983). D. Thesis, Bristol, in preparation. 52. , unpublished. 53. , Koch, C. and Liphard, M. 87. 54. J. (1982). D. Thesis, Bristol. 55. , unpublished. 56. , unpublished; see ref. 45. 29 ADSORPTION FROM SOLUTION 57. See summary of work by Larionov, et al.
6 ) have reported the surface tension for mixtures of n-heptane (A) and cyclohexane (B) at a temperature of 2 9 8 . 1 5 K, and these are shown in Fig. k. 1+2, which is the ratio obtained by vapour phase adsorption on graphon ( 7 ) > and compensates for the nonspherical shape of the n-heptane. A monomolecular surface phase was assumed, with a = 2 . 1 x 1 0 m / m o l , and by using equation ( 1 3 ) K = 1 . U 8 .